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Palladium-catalyzed carbonylation of vinyl halides: a route to the synthesis of .alpha.-methylene lactones

✍ Scribed by Martin, Larry D.; Stille, J. K.


Book ID
126131277
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
491 KB
Volume
47
Category
Article
ISSN
0022-3263

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## Abstract A novel consecutive one‐pot synthesis of pyrazolines and pyrazoles starting from simple aryl halides, styrenes, carbon monoxide, and hydrazines has been established. Palladium‐catalyzed carbonylative vinylation of aryl halides gave the corresponding chalcones, which are trapped in situ