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Palladium-Catalyzed Carbonylation of Propargylamines. Selective Insertion of Carbon Monoxide into a Carbon−Nitrogen Bond

✍ Scribed by Imada, Yasushi; Alper, Howard


Book ID
126305794
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
121 KB
Volume
61
Category
Article
ISSN
0022-3263

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First Insertion Reaction of Carbon Monox
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A solution of ( I l i ) (10 g, 19.3 mmol) in 80 ml of anhydrous toluene, which contains 5 ml ethanol, is heated under reflux for 12 h. The solvent is removed and the residue digested with 50 ml pentane. Precipitated Ph3P0 is separated off and the previously unknown 4,5,6,6a-tetrahydro-2( 1 H)-pental