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Palladium-catalyzed allylation of α-isocyanocarboxylates

✍ Scribed by Yoshihiko Ito; Masaya Sawamura; Masato Matsuoka; Yonetatsu Matsumoto; Tamio Hayashi

Book ID
104227939
Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
230 KB
Volume
28
Category
Article
ISSN
0040-4039

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✦ Synopsis

a-Isocyanocarboxylates underwent palladium-catalyzed allylation with allylic acetates, in which n-allylpalladium(II) intermediate was involved. The catalytic allylation of methyl a-isocyano(phenyl)acetate using an optically active ferrocenylphosphine ligand caused an asymmetric induction of up to 39% ee.

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