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Palladium-Catalyzed Alkoxycarbonylation of ( Z )-2-En-4-yn Carbonates Leading to 2,3,5-Trienoates

✍ Scribed by Akpınar, G. Eray; Kuş, Melih; Üçüncü, Muhammed; Karakuş, Erman; Artok, Levent


Book ID
126429170
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
731 KB
Volume
13
Category
Article
ISSN
1523-7060

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Furan-2-acetic esters are obtained in good yields by direct oxidative cyclization-alkox~.'carbonylation of (Z)-2-en-4-yn-l-ols. bearing both an alkyl or an aD'l substituent a to the hydrox3' group, in the presence of catalytic amounts of palladium iodide in conjunction with potassium iodide at 50-70