Palladium-Catalyzed [3,3] Sigmatropic Rearrangement of (Allyloxy)iminodiazaphospholidines: Allylic Transposition of C—O and C—N Functionality.
✍ Scribed by Ernest E. Lee; Robert A. Batey
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 129 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Scheme 1. Proposed route to allylic amines based on the [3,3] sigmatropic rearrangement of phospholidines 3.
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## Abstract Rearrangement of the pyran‐based aryl enol ethers proceeds with nearly complete diastereoselectivity affording the (E)‐trans products, regardless whether (E)‐ or (Z)‐substrates are being used.