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Palladium-catalyzed [3+2] cycloaddition of 60-fullerene with cis-HOCH2CHCHCH2OCO2Et

✍ Scribed by Clifton K.F. Shen; Chien Kuo-Ming; Liu Tsang-Yu; Lin Tsung-I; Her Guor-Rong; Luh Tien-Yau

Book ID
103401486
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
116 KB
Volume
36
Category
Article
ISSN
0040-4039

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Phosphine-Catalyzed Cycloaddition of Buta-2,3-dienoates and But-2ynoates to (60)Fullerene. -Three phosphine catalysts are tested in the reaction of ( )fullerene ( I) with esters (II) and (IV). PBu3 is found to be the most reactive under the optimized reaction conditions. The structure of product (I