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Palladium-catalyzed [3 + 2] cycloaddition reaction using 2-(sulfonylmethyl)- or 2-(cyanomethyl)allyl carbonate

โœ Scribed by Isao Shimizu; Yukihiro Ohashi; Jiro Tsuji


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
200 KB
Volume
25
Category
Article
ISSN
0040-4039

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Regiospecific synthesis of 2-allyl-1,2,3
โœ Shin Kamijo; Tienan Jin; Zhibao Huo; Yoshinori Yamamoto ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 129 KB

2-Allyl-1,2,3-triazoles were prepared by the palladium-catalyzed three component coupling (TCC) reaction of alkynes, allyl methyl carbonate and trimethylsilyl azide. A p-allylpalladium azide complex, which undergoes the 1,3-dipolar cycloaddition with alkynes, is proposed as a key intermediate in the