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Palladium-catalyzed 1,4-acetoxy-trifluoroacetoxylation of 1,3-dienes

✍ Scribed by Jan-E. Bäckvall; Jan V»gberg; Ruth E. Nordberg

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
278 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

Palladium-catalyzed oxidation of conjugated dienes in acetic acid containing CF3COOH/Li00CCF3 results in the formation of I-acetoxy-4-trifluoroacetoxy-2-alkenes.

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ChemInform Abstract: Palladium-Catalyzed
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Palladium-Catalyzed 1,4-Acetoxy-trifluoroacetoxylation and 1,4-Alkoxy-trifluoroacetoxylation of Cyclic 1,3-Dienes. Scope and Mechanism. -The title products are yielded with good regio-and stereoselectivities. The stereochemical outcome of the acetoxylation of cyclohexadiene (I) can be reversed by

Palladium(0) catalyzed reaction of 1,3-d
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✍ M. Suzuki; Y. Oda; R. Noyori 📂 Article 📅 1981 🏛 Elsevier Science 🌐 French ⚖ 246 KB

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