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Palladium-catalysed nucleophilic release of allylic amines from a phenolic resin

✍ Scribed by Martyn Fisher; Richard C.D Brown

Publisher: Elsevier Science
Year: 2001
Tongue: French
Weight: 126 KB
Volume: 42
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)01739-7

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✦ Synopsis

2°Allylic alcohols were coupled to phenolic polystyrene resin under Mitsunobu conditions to provide substituted allyl ethers, which underwent efficient nucleophilic cleavage by 1°and 2°amines in the presence of catalytic palladium to afford allylic amines.

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