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Palladium catalysed Heck and enantioselective allylic substitution reactions using reverse phase silica supports

✍ Scribed by Michael S Anson; Amin R Mirza; Louise Tonks; Jonathan MJ Williams

Publisher: Elsevier Science
Year: 1999
Tongue: French
Weight: 217 KB
Volume: 40
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(99)01485-9

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✦ Synopsis

The use of reverse phase controlled-pore glass beads in Heck reactions affords the products with low levels of palladium leaching. Additionally, an enantioselective palladium catalysed allylic substitution reaction has been achieved with high enantiomeric excess and a low level of leaching

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