A new diastereo-and regioselective Pd/In bimetallic cascade process which assembles three contiguous chiral centres is described. Pd(0)-catalysed cyclisation of aryl iodides onto proximate 1,3-dienes generates p-allylpalladium(II) species, transmetallation with indium and subsequent Barbier-type add
✦ LIBER ✦
Palladium catalysed cyclisation-Barbier-type allylation cascades
✍ Scribed by Anwar, Usman; Grigg, Ronald; Sridharan, Visuvanathar
- Book ID
- 120040793
- Publisher
- Royal Society of Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 593 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1359-7345
- DOI
- 10.1039/B002713H
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