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Palladium catalysed cyclisation-allene insertion-anion capture cascades

โœ Scribed by Ronald Grigg; Visuvanthar Sridharan; Catherine Terrier


Book ID
103407031
Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
135 KB
Volume
37
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


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The sequential or cascade combination of palladium catalysed cascade cyclisationanion capture involving two-and three-component processes with olefin metathesis, provides access to fused and spirocyclic ring systems in good yield and a bridged ring forming sequence is reported.

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Abstmct: A range qf 6 and m-alkenyl aryl-and vinyl-halides undergo palladium catalysed cyclisation with subsequent tra@er of cyan& ion in the presence of potassimn cyanide (1.2mal) and 1Omol % I&crow&

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We have recently developed 8 wide ranging regio-and stemo-spacific palklium catalysed cascade cyclisation-anion capture process.' The cment !mpe of the process is suamarkd in Table 1.