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Palladium-catalysed amination of halopyridines on a KF-alumina surface

✍ Scribed by Basudeb Basu; Satadru Jha; Niranjan K. Mridha; Md.Mosharef H. Bhuiyan


Book ID
104252103
Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
324 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis


Palladium-catalysed C-N hetero cross-coupling reactions between bromopyridines and amines (both primary and secondary) can be efficiently performed on a KF-alumina (basic) surface, thus negating the use of strong bases such as sodium tert-butoxide. The reaction conditions are optimised with reference to catalytic systems, solvents and the surface.


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Microwave-assisted Suzuki coupling on a
✍ Basudeb Basu; Pralay Das; Md.Mosharef H. Bhuiyan; Satadru Jha πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 254 KB

A range of conjugated polyaryls has been synthesized through one-pot microwave assisted palladium-catalyzed consecutive Suzuki coupling reactions on a KF-alumina surface with notable features including rapid reaction times, solvent-free conditions, high yields, atom economic and air-insensitive reac