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Palladacycles as Reactive Intermediates

✍ Scribed by Dyker, Gerald

Publisher: Wiley (John Wiley & Sons)
Year: 1997
Tongue: English
Weight: 1015 KB
Volume: 130
Category: Article
ISSN: 0009-2940
DOI: 10.1002/cber.19971301104

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📜 SIMILAR VOLUMES

✍ Gerald Dyker 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 139 KB

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This example demonstrates the advantage of ring closure by Wittig reaction: under the usual conditions 2-acetonyl-1,3-cyclohexanedione does not cyclize to (6) but undergoes fragmentati~n[~l. Cyclopentannelation with (bromoacetylmethy1ene)triphenylphosphorane ( I ) is not restricted to stabilized en