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Palladacycles as Reactive Intermediates

โœ Scribed by Gerald Dyker


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
139 KB
Volume
1998
Category
Article
ISSN
1434-1948

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This example demonstrates the advantage of ring closure by Wittig reaction: under the usual conditions 2-acetonyl-1,3-cyclohexanedione does not cyclize to (6) but undergoes fragmentati~n[~l. Cyclopentannelation with (bromoacetylmethy1ene)triphenylphosphorane ( I ) is not restricted to stabilized en