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P5X2+ (X=Br, I), a Phosphorus-Rich Binary P−X Cation with a C2v-Symmetric P5 Cage

✍ Scribed by Ingo Krossing; Ines Raabe

Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
129 KB
Volume
40
Category
Article
ISSN
0044-8249

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✍ Gernot Heckmann; Herbert Binder; Dirk Bongert 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 199 KB

The structure of the compound was deduced from the 119Sn and 31P NMR spectra 3 and it was shown to be a structural analogue of the hetero-nortricyclene The apical phosphorus atom P 4 S 3 . exhibits an extremely negative 31P chemical shift of [554.65 ppm, and the basal phosphorus atoms also resonat