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Oxymercuration of Olefins. II. cis- and trans -Oxymercuration of Bicyclo [2.2.2]oct-2-ene

✍ Scribed by Traylor, T. G.


Book ID
126192446
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
653 KB
Volume
86
Category
Article
ISSN
0002-7863

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Studies on the oxymetalation of olefins
✍ Mitsuru Sakai 📂 Article 📅 1973 🏛 Elsevier Science 🌐 French ⚖ 205 KB

In 1939 Lucas, et al., 1 proposed that the oxymercuration of olefins occurred by a trans addition and that the trans addition proceeded via mercurinium ion intermediates. Recent numerous investigations2 of the oxymercuration of unstrained olefins support the proposed formation of an intermediate mer