Oxygen versus nitrogen coordination of a urea to (diethylenetriamine)platinum(II)
โ Scribed by Woon, Tai Chin; Wickramasinghe, Wasantha A.; Fairlie, David P.
- Book ID
- 120026093
- Publisher
- American Chemical Society
- Year
- 1993
- Tongue
- English
- Weight
- 631 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0020-1669
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๐ SIMILAR VOLUMES
Five-coordinate complexes [PtX 2 (olefin)(2,9-Me 2 -phen)] (1; chloride ions in axial positions. The iodo complexes 1(a-c)z are not oxidized by iodine even under UV irradiation but 2,9-Me 2 -phen = 2,9-dimethyl-1,10-phenanthroline; olefin = ethene denoted by a, propene by b, 1-butene by c; X = Cl re
O-bonded amide complexes of platinum(II), which are stable species due to the higher affinity of platinum for nitrogen donors. In contrast O-bonded amides owe their stability to in acetone solution and which undergo solvolysis in neat water with a rate constant as slow as 8.7โข10 -5 s -1 , are their