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Oxygen-Transfer Reactions of Molybdenum- and Tungstendioxo Complexes Containing η2-Pyrazolate Ligands

✍ Scribed by Kerstin Most; Jens Hoßbach; Denis Vidović; Jörg Magull; Nadia C. Mösch-Zanetti

Publisher: John Wiley and Sons
Year: 2005
Tongue: English
Weight: 189 KB
Volume: 347
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.200404265

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## Abstract Combined CEPT (coupled electron–proton transfer)/OAT (oxygen atom transfer) reactions were accomplished in (Bu~4~N)~2~[Mo^IV^O(bdtCl~2~)~2~] (1) and (Bu~4~N)~2~[Mo^VI^O~2~(bdtCl~2~)~2~] (2) complexes in aqueous media. The reaction mechanism of the CEPT reaction was analyzed electrochemi