Thin (50-500 A) films of cobalt were electrodeposited from sulphate solutions having pH values in the range 1 .9-5 onto thin (001) single-crystal copper substrates . Bicrystals and stripped deposits were examined by transmission electron microscopy and electron diffraction . Deposits from solutions
✦ LIBER ✦
Oxygen storage/release in cobalt porphyrin electrodeposited films
✍ Scribed by Marta Pérez-Morales; Gustavo de Miguel; Eulogia Muñoz; María T. Martín-Romero; Luis Camacho
- Book ID
- 108119324
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 426 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0013-4686
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Facilitated transport of oxygen was investigated in ethyl cellulose membranes containing cobalt(II) meso-tetrakis (substituted phenyl) porphyrins [CoTPP, CoT(2-Cl)PP, CoT(4-Cl)PP, CoT(4-MeO)PP, and CoT(2,4-2MeO)PP] as fixed oxygen carriers. The oxygen permeability (P O 2 ) and oxygen/nitrogen select