Oxygen Binding of Water-Soluble Cobalt Porphyrins in Aqueous Solution
β Scribed by Collman, James P.; Yan, Yi-Long; Eberspacher, Todd; Xie, Xiangjin; Solomon, Edward I.
- Book ID
- 124070520
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 99 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0020-1669
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π SIMILAR VOLUMES
Water-soluble manganese(II1) as well as iron(II1) porphyrinates are introduced as light-sensitive precursor compounds for the photocatalytic activation of dioxygen in aqueous solutions. It is shown that in the presence of a-pinene (4) and the further cycloalkenes 11 -13 photocatalytic oxygenation re
The electrochetiistry of cobalt hematoporphyrin with nitrogen-containing axial ligands has not been reported previously although some complexes with pyridine and cyanide have been investigated by spectrophotometry'. Unlike most complexes of cobalt(II1) which are not very labile, the hematoporphyrin
## Concentration dependence of catalysis In Fig. 3A, the CV i-E curves are shown for airsaturated