Water-soluble manganese(II1) as well as iron(II1) porphyrinates are introduced as light-sensitive precursor compounds for the photocatalytic activation of dioxygen in aqueous solutions. It is shown that in the presence of a-pinene (4) and the further cycloalkenes 11 -13 photocatalytic oxygenation re
β¦ LIBER β¦
Electrocatalytic oxygenation of alkenes by a sterically hindered water-soluble iron porphyrin in aqueous solutions
β Scribed by Tzung-shian Lee; Y. Oliver Su
- Publisher
- Elsevier
- Year
- 1996
- Tongue
- English
- Weight
- 432 KB
- Volume
- 414
- Category
- Article
- ISSN
- 1572-6657
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Epoxidation of Olefins by a Water-Soluble Iron(III) Porphyrin Complex and Hydroperoxides in Aqueous Solution. -Based on the results of the title reaction of (I) with different olefins (II)-(IV) and comparison with other oxidants the possible mechanism is discussed. Preliminary studies concerning ste