The rate of oxygen recombination (i.e., reduction) on plastic-bonded cadmium electrodes in sealed Ni-Cd systems can be controlled over a wide range by doping the negative active material with Ni(OH),, FeaOb or carbon black. The highest recombination rate was attained by combining all these additives
Oxygen recombination rate on plastic-bonded cadmium electrodes doped with nickel(II) hydroxide
✍ Scribed by S. Petrovič; J. Garche; K. Wiesener; J. Mrha; J. Jindra
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 575 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0378-7753
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✦ Synopsis
It was found that the rate of reduction of oxygen on plastic-bonded cadmium electrodes doped with Nl(OH), is highest when the added nickel amounts to 0.3%. If the active material 1s in prolonged contact with a solution of NISOq and then alkahzed, its oxygen reduction activity is appreciably lowered, probably owing to a cementation reaction glvmg metalhc nickel
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The oxygen recombination (reduction) rate on plastic-bonded cadmium electrodes in sealed Ni-Cd systems can be increased by using metal screens applied to the gas side of the plastic-bonded cadmium electrode. The metal screen applied should have an optimum geometry (mesh size, wire diameter) to prov