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Oxygen exchange between tris(oxalato)rhodate(III) ion and solvent water. Exchange of outer and inner oxygens

โœ Scribed by Damrauer, Lenore.; Milburn, Ronald M.

Book ID
126838655
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
259 KB
Volume
90
Category
Article
ISSN
0002-7863

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It is generally believed [l] that vanadium(IV) perchlorate in acidic aqueous solution exists in the form WW2>51 2+. A unique feature of the ion is the multiple bond between V(IV) and one of the ligand oxygens giving a strong axial symmetry to the molecule. This results in three types of oxygens coor