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Rates of oxygen exchange between vanadyl ion (VO2+) and water

✍ Scribed by R. Kent Murmann

Publisher: Elsevier Science
Year: 1977
Tongue: English
Weight: 203 KB
Volume: 25
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)95636-6

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✦ Synopsis

It is generally believed [l] that vanadium(IV) perchlorate in acidic aqueous solution exists in the form WW2>51 2+. A unique feature of the ion is the multiple bond between V(IV) and one of the ligand oxygens giving a strong axial symmetry to the molecule. This results in three types of oxygens coordinated to a single positive ion center, 0

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