Oxygen Donor Stabilized Alkaline Earth Metal Iodides
β Scribed by Katharina M. Fromm
- Publisher
- John Wiley and Sons
- Year
- 2003
- Weight
- 49 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0931-7597
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We report a detailed computationally study of the stability of the alkaline earth metal peroxides MO 2 (M β«Ψβ¬ Ba, Sr, Ca, Mg, Be) with respect to decomposition into the corresponding oxides MO and molecular oxygen using Hartree-Fock and density functional theory (DFT) techniques. A comparison betwee
A known amount of lithium or calcium nitrate solution is added to the sample powder which is then heated in air or oxygen. The oxygen in test samples of UO,+,, SrO.,UO.,O,+, and SrO.,UO.,O,+, was determined with an estimated standard deviation of +\_ 0.002.
An experimental method was developed to determine the stability constants with nearly insoluble ligands in homogeneous solution. This method was tested using dibenzo crown ethers, which have a very low solubility in aqueous solution. The stability constants for the complexation of alkali and alkalin