𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Oxygen atom and imido group transfer reactions of Mo and V

✍ Scribed by E.W. Harlan; Y.-P. Zhang; R.H. Holm

Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
70 KB
Volume
36
Category
Article
ISSN
0162-0134

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Studies on the oxygen atom transfer reac
Studies on the oxygen atom transfer reactions of peroxomonosulfate: Oxidation of glycolic acid
✍ S. Shailaja; M. S. Ramachandran πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 118 KB

## Abstract The kinetics of oxidation of glycolic acid, an α‐hydroxy acid, by peroxomonosulfate (PMS) was studied in the presence of Ni(II) and Cu(II) ions and in acidic pH range 4.05–5.89. The metal glycolate, not the glycolic acid (GLYCA), is oxidized by PMS. The rate is first order in [PMS] and

Studies on the oxygen atom transfer reac
Studies on the oxygen atom transfer reactions of peroxomonosulfate: Oxidation of lactic acid
✍ P. Andal; M. Murugavelu; S. Shailaja; M. S. Ramachandran πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 111 KB

## Abstract Kinetics of oxidation of lactic acid by peroxomonosulfate (PMS) catalyzed by Ni(II) ions has been studied in aqueous buffered (sodium acetate‐acetic acid) medium. The reaction follows first order in [PMS] and [Ni(II)] and inverse first order in [H^+^]. The effect of pH on the rate sugge

Studies on the oxygen atom transfer reac
Studies on the oxygen atom transfer reactions of peroxomonosulfate: Catalytic effect of hemiacetal
✍ S. Shailaja; M. S. Ramachandran πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 121 KB

## Abstract The reaction of peroxomonosulfate (PMS) with glycolic acid (GLYCA), an alpha hydroxy acid, in the presence of Ni(II) ions and formaldehyde was studied in the pH range 4.05–5.89 and at 31Β°C and 38Β°C. When formaldehyde and Ni(II) ions concentrations are ∼5.0 Γ— 10^βˆ’4^ M to 10.0 Γ— 10^βˆ’4^ M,