Oxygen- and Temperature-Dependent Kinetic Isotope Effects in Choline Oxidase: Correlating Reversible Hydride Transfer with Environmentally Enhanced Tunneling

Temperature Dependence of the Primary Ki

Temperature Dependence of the Primary Kinetic Isotope Effect in Hydride Transfer Reactions with NAD+and NADH Models

✍ Vladimir Leskovac; Svetlana Trivić; Emilija Nikolić-Djorić 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 160 KB

N 1 -(2,6-dichlorobenzyl)-1,4-( 1 H 2 )dihydronicotinamide and N 1 -(2,6-dichlorobenzyl)-1,4-( 1 H, 2 H)dihydronicotinamide were oxidized with nitrosobenzene (NOB), 2,6-dichloroindophenol (DCPIP), 2,4,6-trinitrobenzenesulfonic acid (TNBS), 10-methyl-acridinium ion (MAI), and 10-methyl-9-phenyl-acrid