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Oxyfunctionalization of Non-Natural Targets by Dioxiranes. 4. 1 Efficient Oxidation of Binor S Using Methyl(trifluoromethyl)dioxirane

โœ Scribed by D'Accolti, Lucia; Fusco, Caterina; Lucchini, Vittorio; Carpenter, Gene B.; Curci, Ruggero

Book ID
126927850
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
96 KB
Volume
66
Category
Article
ISSN
0022-3263

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Oxidation of natural targets by dioxiran
Oxidation of natural targets by dioxiranes. Part 4: A novel approach to the synthesis of N-hydroxyamino acids using dioxiranes
โœ Antonia Detomaso; Ruggero Curci ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 80 KB

An efficient approach to the synthesis of N-hydroxyamino acids in high enantiomeric excess is described; this involves the high-yielding selective N-hydroxylation of N-Boc protected primary amino acid esters with methyl(trifluoromethyl)dioxirane under mild conditions.