𝔖 Bobbio Scriptorium
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Oxydimetrische Bestimmung von Mercaptanen mit Brom und Blei(IV)-acetat

✍ Scribed by Karl Georg Häusler; Rudolf Geyer; Siegfried Rennhak


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
255 KB
Volume
14
Category
Article
ISSN
0044-2402

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✍ G. Cainelli; B. Kamber; J. Keller; M. Lj. Mihailović; D. Arigoni; O. Jeger 📂 Article 📅 1961 🏛 John Wiley and Sons 🌐 German ⚖ 709 KB

The influence of the environment of the hydroxyl group on the course of the oxidation of 20‐hydroxy‐steroids with lead tetraacetate has been investigated. It could be shown that, whenever the normal reaction — ether formation between C‐18 and C‐20 — is inhibited by steric factors, fragmentation proc