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Oxothiomolybdenum Derivatives of the Superlacunary Crown Heteropolyanion {P 8 W 48 }: Structure of [K 4 {Mo 4 O 4 S 4 (H 2 O) 3 (OH) 2 } 2 (WO 2 )(P 8 W 48 O 184 )] 30– and Studies in Solution

✍ Scribed by Korenev, Vladimir S.; Floquet, Sébastien; Marrot, Jérôme; Haouas, Mohamed; Mbomekallé, Israël-Martyr; Taulelle, Francis; Sokolov, Maxim N.; Fedin, Vladimir P.; Cadot, Emmanuel


Book ID
121448444
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
524 KB
Volume
51
Category
Article
ISSN
0020-1669

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✍ Marie-Anne Pilette; Sébastien Floquet; Jérôme Marrot; Emmanuel Cadot 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 567 KB

The [(P 4 W 34 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }] 16-anion was obtained by the stereospecific addition of the [Mo 2 S 2 O 2 ] 2+ oxothio cation to the monovacant α 2 -[P 2 W 17 O 61 ] 10-anion. The mixed salt K 9 Na 7 [(P 2 W 17 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }]•50H 2 O was isolated as single cry