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ChemInform Abstract: Oxothiomolybdenum Derivatives of the Superlacunary Crown Heteropolyanion {P8W48}: Structure of [K4{Mo4O4S4 (H2O)3(OH)2}2(WO2) (P8W48O184)]30- and Studies in Solution.

✍ Scribed by Vladimir S. Korenev; Sebastien Floquet; Jerome Marrot; Mohamed Haouas; Israel-Martyr Mbomekalle; Francis Taulelle; Maxim N. Sokolov; Vladimir P. Fedin; Emmanuel Cadot


Book ID
112043592
Publisher
John Wiley and Sons
Year
2012
Weight
31 KB
Volume
43
Category
Article
ISSN
0931-7597

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The [(P 4 W 34 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }] 16-anion was obtained by the stereospecific addition of the [Mo 2 S 2 O 2 ] 2+ oxothio cation to the monovacant Ξ± 2 -[P 2 W 17 O 61 ] 10-anion. The mixed salt K 9 Na 7 [(P 2 W 17 O 61 ) 2 {Mo 4 S 4 O 4 (OH 2 ) 2 }]β€’50H 2 O was isolated as single cry