Oxorhenium(V) complexes with naphtholate-oxazoline ligands in the catalytic epoxidation of olefins
✍ Scribed by Terfassa, Belina; Schachner, Jörg A.; Traar, Pedro; Belaj, Ferdinand; Mösch Zanetti, Nadia C.
- Book ID
- 122300149
- Publisher
- Elsevier Science
- Year
- 2014
- Tongue
- English
- Weight
- 739 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0277-5387
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The catalytic activity of two manganese(III)-oxazoline complexes [Mn(phox) 2 (CH 3 OH) 2 ]ClO 4 and Mn(phox) 3 (Hphox = 2-(2 -hydroxylphenyl)oxazoline), was studied in the epoxidation of various olefins. All of epoxidation reactions were carried out in (1:1) mixture of methanol:dichloromethane at ro
Dioxomolybdenum(VI) complexes with the general formula [MoO 2 X 2 (N,N)] (X = Cl, OSiPh 3 ) containing a chiral bidentate oxazoline ligand (N,N = 2,2 -bis[(4S)-4-benzyl-2-oxazoline]) have been prepared and characterised by 1 H NMR, IR spectroscopy and thermogravimetric analysis. The bis(chloro) comp