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Nonheme iron(II) complexes of macrocyclic ligands in the generation of oxoiron(IV) complexes and the catalytic epoxidation of olefins

✍ Scribed by Yumi Suh; Mi Sook Seo; Kwan Mook Kim; Youn Sang Kim; Ho G. Jang; Takehiko Tosha; Teizo Kitagawa; Jinheung Kim; Wonwoo Nam


Book ID
108174925
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
251 KB
Volume
100
Category
Article
ISSN
0162-0134

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Nonheme Iron(II) Complexes of Macrocycli
✍ Yumi Suh; Mi Sook Seo; Kwan Mook Kim; Youn Sang Kim; Ho G. Jang; Takehiko Tosha; πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons βš– 8 KB πŸ‘ 1 views

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The catalytic activity of two manganese(III)-oxazoline complexes [Mn(phox) 2 (CH 3 OH) 2 ]ClO 4 and Mn(phox) 3 (Hphox = 2-(2 -hydroxylphenyl)oxazoline), was studied in the epoxidation of various olefins. All of epoxidation reactions were carried out in (1:1) mixture of methanol:dichloromethane at ro

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The complex [Fe(imox) (Nmim)~], where imox is a planar bis(iminooxime) macrocyclic ligand and Nmim = N-methyl imidazole, undergoes substitution reactions in the presence of 2,2'bipyridine (bipy), leading to a series of intermediate mixed complexes. The forward and reverse rate constants for the subs