Nonheme Iron(II) Complexes of Macrocyclic Ligands in the Generation of Oxoiron(IV) Complexes and the Catalytic Epoxidation of Olefins
✍ Scribed by Yumi Suh; Mi Sook Seo; Kwan Mook Kim; Youn Sang Kim; Ho G. Jang; Takehiko Tosha; Teizo Kitagawa; Jinheung Kim; Wonwoo Nam
- Publisher
- John Wiley and Sons
- Year
- 2006
- Weight
- 8 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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## Abstract We have shown previously that iodosylbenzene–iron(III) porphyrin intermediates (2) are generated in the reactions of oxoiron(IV) porphyrin π‐cation radicals (1) and iodobenzene (PhI), that 1 and 2 are at equilibrium in the presence of PhI, and that the epoxidation of olefins by 2 afford