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Oxorhenium(V) Complexes of Carbohydrate Ligands

✍ Scribed by Peter Klüfers; Oswald Krotz; Martin Oßberger


Book ID
101348832
Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
150 KB
Volume
2002
Category
Article
ISSN
1434-1948

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Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give