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Synthesis of “3+1” mixed-ligand oxorhenium(V) complexes containing modified 3,17β-estradiol

✍ Scribed by Frank Wüst; Hartmut Spies; Bernd Johannsen


Book ID
104364636
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
206 KB
Volume
6
Category
Article
ISSN
0960-894X

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✦ Synopsis


Two rhenium "3+1" mixed-ligand complexes bearing an estradiol moiety were prepared. The small-sized rhenium chelate units were introduced by two different rhenium precursors to give stable complexes in satisfactory yields.


📜 SIMILAR VOLUMES


Synthesis and Structural Characterizatio
✍ Reisgys, Martina ;Spies, Hartmut ;Johannesn, Bernd ;Pietzsch, Hans-Jergen ;Leibn 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 493 KB 👁 1 views

Neutral oxorhenium(V) complexes with dithioether ligands of the general formula [ReOX3(RS[CHz]2SR)], X = C1, Br, R = nBu, Et, Bzl were synthesized. Ammonium perrhenate reacts in concentrated hydrochloric acid with dithiaalkanes (RS[CH2I2SR, R = nBu, Et, Bzl) dissolved in glacial acetic acid to give