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Oxoperoxo molybdenum(vi) and tungsten(vi) and oxodiperoxo molybdate(vi) and tungstate(vi) complexes with 8-quinolinol: synthesis, structure and catalytic activity

✍ Scribed by Maiti, Swarup K.; Banerjee, Surajit; Mukherjee, Alok K.; Abdul Malik, K. M.; Bhattacharyya, Ramgopal

Book ID
120327483
Publisher
Royal Society of Chemistry
Year
2005
Tongue
English
Weight
786 KB
Volume
29
Category
Article
ISSN
1144-0546

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## Abstract Reaction of WX~6~ (X = Cl or Br) with O(SiMe~3~)~2~ in CH~2~Cl~2~, followed by addition of MeCN and a further equivalent of O(SiMe~3~)~2~ in CH~2~Cl~2~ gives [WO~2~X~2~(MeCN)~2~] in situ, which subsequently react with the dithioethers MeS(CH~2~)~2~SMe, __i__PrS(CH~2~)~2~S__i__Pr or 1,4‐