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Oxomolybdenum coordination compounds with alkyl-substituted pyridines. Solvothermal syntheses and structural characterization of [Mo10O26(3,5-Lut)8]·2(3,5-Lut), [Mo10O26(3-MePy)8]·(3-MePy), [Mo10O26(3-MePy)8] and [Mo12O28(OCH3)2Cl2(3-MePy)8]

✍ Scribed by Barbara Modec; Jurij V Brenčič; Ljubo Golič; Lee M Daniels

Book ID
108427934
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
402 KB
Volume
19
Category
Article
ISSN
0277-5387

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Solid-State Coordination Chemistry of Mo
Solid-State Coordination Chemistry of Molybdenum Oxides with di-2-Picolylamine (pca): The Hydrothermal Syntheses and Structures of the Molecular Cluster [{Ni(pca)(H2O) }2Mo8O26], the Two-Dimensional [{Cu(pca)}2Mo8O26], and theOne-Dimensional [{Cu3(pca)3MoO4}Mo8O26]
✍ Randy S. Rarig Jr.; Jon Zubieta 📂 Article 📅 2002 🏛 Elsevier Science 🌐 English ⚖ 217 KB

## IN HONOR OF PROFESSOR GALEN STUCKY ON THE OCCASION OF HIS 65TH BIRTHDAY The hydrothermal reaction of di-2-picolylamine (pca), MoO 3 and NiSO 4 '6H 2 O yielded the bimetallic oxide cluster [{Ni (pca)(H 2 O)} 2 Mo 8 O 26 ]'2H 2 O (1'2H 2 O). Similarly, the reaction of pca, MoO 3 and CuSO 4 '5H 2