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Oxo-titanium and -zirconium diphosphines [(η-C5H5)2M(CH2PPh2]2O (with M = Ti, Az) as building blocks for heterobimetallic complexes

✍ Scribed by Francois Senocq; Mario Basso-Bert; Robert Choukroun; Daniele Gervais

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
237 KB
Volume
297
Category
Article
ISSN
0022-328X

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The Influence of the Ligands Cp*(η5-C5Me
The Influence of the Ligands Cp*(η5-C5Me5) and Cp(η5-C5H5) on the Stability and Reactivity of Titanocene and Zirconocene Complexes: Reactions of the Bis(trimethylsilyl)acetylene Permethylmetallocene Complexes (η5-C5Me5)2M(η2-Me3SiC2SiMe3), M = Ti, Zr, with H2O and CO2
✍ Paul-Michael Pellny; Vladimir V. Burlakov; Wolfgang Baumann; Anke Spannenberg; U 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB 👁 1 views

The reactions of the bis(trimethylsilyl)acetylene permethylmetallocene complexes Cp 2 M(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (1), M = Zr (2)) with H 2 O and CO 2 were studied and compared to those of the corresponding metallocene complexes Cp 2 M(L)(g 2 -Me 3 SiC 2 SiMe 3 ) (M = Ti (3), L = ± ; M = Zr,