Oxidative Spaltung von Triethylentetramin (trien) unter Bildung von Diethylentriamin (dien) und Struktur des siebenkernigen MnII/MnIII-Komplexes [Mn7(trien)2(dien)2O4(OAc)8](PF6)4 · 2H2O

Oxidative Cleavage of Triethylenetetrami

Oxidative Cleavage of Triethylenetetramine (trien) to Yield Diethylenetriamine (dien): Structure of the MnII/MnIII Heptanuclear Complex [Mn7(trien)2(dien)2O4(OAc)8](PF6)4·2H2O

✍ Dr. Rajumati Bhula; Dr. David C. Weatherburn 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 English ⚖ 261 KB

The stereoselective reaction sequences presented here enable the synthesis of numerous heterocyclic ring systems. Depending upon the oxime system used, the reaction sequences lead with ring expansion to products of the azepane type or by direct cyclization to products of the perhydroquinoline type,