Oxidative polydehydrocondensation of bis-2-propynyloxy compounds containing silicon, phosphorus, and fluorine
β Scribed by A. G. Makhsumov; A. M. Sladkov; V. V. Korshak
- Book ID
- 112419527
- Publisher
- Springer
- Year
- 1964
- Tongue
- English
- Weight
- 223 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
The hydrolysis of 1,2-bis(5,6-benzo-1-methyl-2chloro-1,3,2-diazaphosphorin-4-on-3-yl)ethane (1) and its 1,3-propane derivative (2) with excess water led, without decomposition, to the formation of the bis-phosphoryl compounds 3 and 4. Reaction of 1 and 2 with bis(trimethylsiloxy)ethane formed the sy
state is again in accordance with the idea that ring closure to a diaziridine is favoured in the first excited state as also indicated by the PPP calculation. This work is part of project No. SR 2.120.69 of the Schweizerischer Nationalfonds. Financial support by CIl3A-GEIGY A G and a generous gift