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Unsaturated nitrogen compounds containing fluorine. Part 17. The reactions of 3,5-bis(trifluoromethyl)-1H-1,2,4-triazole with alkynes, alkenes and diazomethane, and of sodium 3,5-bis(trifluoromethyl)-1,2,4-triazolide with halogen compounds

โœ Scribed by Mohamad M. Abdul-Ghani; Anthony E. Tipping


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
1003 KB
Volume
72
Category
Article
ISSN
0022-1139

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Synthesis of 3,4-dihydro-2h-thiopyrans b
โœ Hiroshi Maruoka; Kenji Yamagata; Motoyoshi Yamazaki ๐Ÿ“‚ Article ๐Ÿ“… 2002 ๐Ÿ› Journal of Heterocyclic Chemistry ๐ŸŒ English โš– 32 KB

## Abstract Sulfonium ylides **1aโ€h** reacted with sodium iodide to afford the corresponding thiopyrans **2aโ€h.** On the other hand, compounds **1aโ€d** were treated with thionyl chloride to give the ring opening products **3aโ€d.** The reaction of compounds **3aโ€d** with sodium iodide and triethylam