Oxidative Dissolution of Silver Nanoparticles by Biologically Relevant Oxidants: A Kinetic and Mechanistic Study
β Scribed by Chi-Ming Ho; Sammi King-Woon Yau; Chun-Nam Lok; Man-Ho So; Chi-Ming Che
- Book ID
- 112005837
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 424 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1861-4728
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## Abstract Kinetics of oxidation of indoleβ3βacetic acid (IAA) by peroxomonosulphate (PMS) in aqueous acetonitrile medium has been investigated. The reaction follows a total second order, first order each with respect to [IAA] and [PMS]. The rate of the reaction was not affected by added [H^+^]. V
The kinetics of the oxidation of naphthalene and phenanthrene by pyridinium fluorochromate, C5H,NHCrO3F, PFC, has been studied. The main product of the oxidation is the corresponding quinone. While each oxidation, studied in aqueous acetic acid (80-95%, v / v ) medium, is first order with respect to