𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Oxidation of naphthalene and phenanthrene by pyridinium fluorochromate (PFC)—a kinetic and mechanistic study

✍ Scribed by Bharati Bhattacharjee; Manabendra N. Bhattacharjee; Mitra Bhattacharjee; Apurba K. Bhattacharjee

Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
409 KB
Volume
17
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis

The kinetics of the oxidation of naphthalene and phenanthrene by pyridinium fluorochromate, C5H,NHCrO3F, PFC, has been studied. The main product of the oxidation is the corresponding quinone. While each oxidation, studied in aqueous acetic acid (80-95%, v / v ) medium, is first order with respect to the oxidant, the rate is almost independent of the substrate concentration. The reactions are catalyzed by acid, the acid-catalyzed reactions being very fast, which precluded determination of their order in acid medium. The kinetic isotope effect, k H / k D is 5.50 a t 303 K for naphthalene. The reaction does not induce polymerization of acrylonitrile. The effects of temperature and solvent compositions were studied and activation parameters evaluated. Probable mechanisms are discussed.

📜 SIMILAR VOLUMES

Oxidation of indole-3-acetic acid by per
Oxidation of indole-3-acetic acid by peroxomonosulphate: A kinetic and mechanistic study
✍ G. Chandramohan; S. Kalyanasundharam; R. Renganathan 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 127 KB 👁 1 views

## Abstract Kinetics of oxidation of indole‐3‐acetic acid (IAA) by peroxomonosulphate (PMS) in aqueous acetonitrile medium has been investigated. The reaction follows a total second order, first order each with respect to [IAA] and [PMS]. The rate of the reaction was not affected by added [H^+^]. V

Oxidation of isoniazid by N-haloarenesul
Oxidation of isoniazid by N-haloarenesulfonamidates in alkaline medium: A kinetic and mechanistic study
✍ Puttaswamy; T. M. Anuradha; R. Ramachandrappa; N. M. Made Gowda 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 211 KB 👁 2 views

The kinetics of oxidation of Isoniazid (INH) by sodium N-haloarenesulfonamidates, chloramine-T (CAT), bromamine-T (BAT), chloramine-B (CAB), and bromamine-B (BAB), has been studied in alkaline medium at 303 K. The oxidation reaction follows identical kinetics with a first-order dependence on each [o

Oxidation of some α-hydroxy acids by tet
Oxidation of some α-hydroxy acids by tetraethylammonium chlorochromate: A kinetic and mechanistic study
✍ Preeti Swami; D. Yajurvedi; P. Mishra; Pradeep K. Sharma 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 96 KB

## Abstract The oxidation of glycolic, lactic, malic, and a few substituted mandelic acids by tetraethylammonium chlorochromate (TEACC) in dimethylsulfoxide leads to the formation of corresponding oxoacids. The reaction is first order each in TEACC and hydroxy acids. Reaction is failed to induce th

A kinetic and mechanistic study on the o
A kinetic and mechanistic study on the oxidation of indole-3-acetic acid by peroxodisulfate
✍ S. Kalyanasundharam; G. Chandramohan; M. Suresh; V. Anbazhagan,; S. Lavanya; R. 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 111 KB 👁 1 views

## Abstract The kinetics of oxidation of indole‐3‐acetic acid (IAA) by peroxodisulfate (PDS) has been carried out in aqueous acetic acid medium. First‐order dependence of rate each with respect to [IAA] and [PDS] was observed. The reaction rate was unaffected by added [H^+^]. Increase of percentage

Kinetic and mechanistic studies on the o
Kinetic and mechanistic studies on the oxidation of nitrite by peroxomonophosphoric acid
✍ Ganesh Prasad Panigrahi; Ramanando Nayak 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 English ⚖ 282 KB 👁 1 views

The kinetics of oxidation of nitrite to nitrate by peroxornonophosphoric acid in aqueous acid medium have been studied. The observed monotonic fall in rate with increasing pH of the medium has been rationalized on the basis of proton-dissociation equilibria of the substrate as well as the oxidant sp

Oxidation of some primary amines by brom
Oxidation of some primary amines by bromamine-B in alkaline medium: A kinetic and mechanistic study
✍ S. Ananda; T. Demappa; D. S. Mahadevappa; N. M. Made Gowda 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 359 KB 👁 2 views

The kinetics of oxidation of the aliphatic primary amines, n-propylarnine, n-butylarnine, and isoarnylarnine, by sodium N-brornobenzenesulfonarnide or bromamine-B (BAB) in sodium hydroxide medium has been studied at 35" C The reaction rate shows a First-order dependence each on [ BABl and [amine]. a