β Scribed by M.T. Abilov; V.A. Golodov
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π SIMILAR VOLUMES
It has been reported that degradation of carbohydrates by alkaline hydrogen peroxide can take place by the Fenton reaction1-3, the Bayer-Villiger reaction4, the alpha hydraxy hydroperoxide (aHHP) cleavage-reaction>', the ester reaction', the dihydroxy-epoxide reaction"', and the peroxy-radical react
Previously we described the efficient oxidation of l-methoxycyclopropanol 1 with Cu\*+ Ions to methyl acrylate 2 and dimethyl adipate 3 via the methyl P-propionate radical 2. It was proved by labelling experiments 131 that the \*
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The oxidation of triphenylphosphine to the corresponding oxide in pyridine is faster in the presence ofFe m compounds, especially FeCI3. Even greater effects are seen for the oxidation oftrimethyl phosphite.