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Catalysis of the oxidation of triphenylphosphine and of trimethyl phosphite by hydrogen peroxide in the presence of FeIII compounds

✍ Scribed by Derek H.R. Barton; David R. Hill; Bin Hu

Publisher: Elsevier Science
Year: 1997
Tongue: French
Weight: 98 KB
Volume: 38
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(97)00177-9

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✦ Synopsis

The oxidation of triphenylphosphine to the corresponding oxide in pyridine is faster in the presence ofFe m compounds, especially FeCI3. Even greater effects are seen for the oxidation oftrimethyl phosphite.

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