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Oxidative dehydrodimerization of manganese vinylidene complexes (η5-C5R5)(CO)(L)MnCCHPh (R = Me, L = CO; R = H, L = PPh3)

✍ Scribed by Lyudmila N. Novikova; Mikhail G. Peterleitner; Karine A. Sevumyan; Oleg V. Semeikin; Dmitri A. Valyaev; Nikolai A. Ustynyuk

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
156 KB
Volume
16
Category
Article
ISSN
0268-2605

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📜 SIMILAR VOLUMES

Reactivity of the Inversely Polarised Ar
Reactivity of the Inversely Polarised Arsaalkenes R–As=C(NMe2)2 {R = [(η5-C5Me5)(CO)2Fe], tBuC(O)} Towards Vinylidene Complexes [η5-(C5H5)(CO)(NO)W=C=C(H)R] (R = Ph, tBu)
✍ Lothar Weber; Philipp Bayer; Gabriel Noveski; Hans-Georg Stammler; Beate Neumann 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 177 KB

## Abstract The reaction of the vinylidene complexes [(C~5~H~5~)(CO)(NO)W=C=C(H)R] (10a: R = __t__Bu; 10b: R = Ph) with the arsaalkene __t__BuC(O)–As=C(NMe~2~)~2~ (11) afforded the novel η^2^‐1‐arsaallene complexes [η^2^‐{__t__BuC(O)–As=C=C(H)R}W(CO)(NO)C~5~H~5~] (13: R = __t__Bu; 15: R = Ph). Simi