The decarboxylation of [1-13 C]leucine by peroxyl radicals (ROO β’ ) has been studied by using combined gas chromatography/isotope ratio mass spectrometry (GC/IRMS) to follow the production of 13 CO 2 . Peroxyl radicals were obtained by thermal decomposition of a water soluble azo initiator, 2,2'-azo
β¦ LIBER β¦
Oxidative Decarboxylation of Benzoic Acid by Peroxyl Radicals
β Scribed by R Lamrini; P Lacan; A Francina; R Guilluy; M Desage; J Michon; M Becchi; J.L Brazier
- Book ID
- 114276727
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 198 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0891-5849
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## Abstract Cyclohexanecarboxylic acid is converted to a mixture of cyclohexanone and cyclohexene by reacting it at temperatures around 200Β° with an oxygenβcontaining gas and steam in the presence of metalβsalt catalysts.