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Oxidative decarboxylation of arylacetic acids by means of tetrabutylammonium periodate

โœ Scribed by Enzo Santaniello; Federico Ponti; Ada Manzocchi


Publisher
Elsevier Science
Year
1980
Tongue
French
Weight
135 KB
Volume
21
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES


Oxidative decarboxylation of arylacetic
โœ Yong Il Kim; Yong Hae Kim ๐Ÿ“‚ Article ๐Ÿ“… 1998 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 190 KB

The oxidative decarboxylation of aryl, a, a-diaryl, or arylalkylacetic acids has been achieved by a 2-nitrobenzenesulfonyl peroxy radical intermediate (1) generated by the reaction of 2-nilrobenzenesulfonyl chloride with potassium superoxide at -20"(3 in dry acetonitrile.

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Oxidative decarboxylation of carboxylic acids by a supported manganese (III) porphyrin was investigated. In the chemical system using 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatomanganese (III) chloride supported on crosslinked chloromethylated polystyrene, [Mn(H 2 NTPP)-CMP], as catalyst, carboxy