Oxidative decarboxylation of arylacetic acids by means of tetrabutylammonium periodate
โ Scribed by Enzo Santaniello; Federico Ponti; Ada Manzocchi
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- French
- Weight
- 135 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
The oxidative decarboxylation of aryl, a, a-diaryl, or arylalkylacetic acids has been achieved by a 2-nitrobenzenesulfonyl peroxy radical intermediate (1) generated by the reaction of 2-nilrobenzenesulfonyl chloride with potassium superoxide at -20"(3 in dry acetonitrile.
Oxidative decarboxylation of carboxylic acids by a supported manganese (III) porphyrin was investigated. In the chemical system using 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatomanganese (III) chloride supported on crosslinked chloromethylated polystyrene, [Mn(H 2 NTPP)-CMP], as catalyst, carboxy